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 报告题目: Tackling CO2 Issues by Chemical Conversion and by Reducing CO2 Emission
  
 开始时间: 2018-07-20 09:30:00
  
 报告地点: 徐汇校区实验四楼207室
  
 报 告 人: 陈经广教授(Prof. Jingguang Chen. Columbia University, USA)
  
 主办单位: 化学与分子工程学院计算化学中心
  
 备    注:

备    注:Jingguang Chen is the Thayer Lindsley Professor of chemical engineering at Columbia University, with a joint appointment as a senior chemist at Brookhaven National Laboratory.  He is also a Thousand Talent professor at Tsinghua University.  He is the co-author of over 20 United States patents and over 360 journal publications. He is currently the President of the North American Catalysis Society and an Associate Editor of ACS Catalysis. He received many catalysis awards, including the 2015 George Olah award from the American Chemical Society and the 2017 Robert Burwell Lectureship from the North American Catalysis Society.

摘    要:Emission of CO2, a byproduct from many industrial processes and power plants, has increased with increasing energy demand and growing population. Most of the efforts to chemically reduce CO2 requires the use of H2. This is not desirable because at present ~95% of H2 is generated from hydrocarbon-based feedstock, producing CO2 as a byproduct.  In this talk we will first give a brief summary on CO2 conversion by H2 [1,2], followed by discussing our recent efforts in converting CO2 by light alkanes, such as ethane, via the dry reforming pathway to produce synthesis gas (C2H6 + 2CO2 → 4CO + 3H2) or the oxidative dehydrogenation route to generate ethylene (C2H6 + CO2 → C2H4 + CO + H2O). Using a combination of kinetic studies, in situ characterization and DFT calculations, we have identified several classes of catalysts that can activate both CO2 and light alkanes (C2-C4) [3] to achieve selective dry reforming or oxidative dehydrogenation. Finally, we will discuss alternative pathways for N2 transformations, which are the most CO2-emitting chemical processes [4].
[1] S. Kattel, P. Liu and J.G. Chen, Journal of the American Chemical Society, 139 (2017) 9739.
[2] S. Kattel, P.J. Ramírez, J.G. Chen, J.A. Rodriguez and P. Liu, Science, 355 (2017) 1296.
[3] E. Gomez, S. Kattel, B. Yan, S. Yao, P. Liu and J.G. Chen, Nature Communications, 9 (2018) 1398.
[4] J.G. Chen, R.M. Crooks, L.C. Seefeldt, et al. Science, 360 (2018) 873.